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Formation and selected reactions of some binuclear oxygen complexes
(1977)
Chelate formation and amide deprotonation reactions of 1:1 cobaltous complexes of glycyl-L-histidine, glycylhistamine, glycyl-L-aspartic acid, L-histidyl-L-histidine, L-histidylglycine, and L-aspartylglycine have been ...
Catalysis of [beta]-elimination of amino acids by pyridoxal and metal ions
(1978)
The kinetics and equilibrium measurements of a-amino acids have been investigated, under β-elimination conditions, in the presence of pyridoxal with and without catalytic metal ions. The nmr technique was applied to several ...
Electronic structure of peroxo and superoxo polyamine cobalt (III) complexes
(1978)
Electronic spectra of two mononuclear cobalt(III) superoxides, [Co(CN)₅O₂]³⁻ and [Co(s-Me₂en)₂0₂Cl] ⁺ where s-Me₂en is N,N'-dimethylethylenediamine, have been studied. An unusually low intensity for the low energy MLCT ...
Interactions and catalysis in normal and reversed micellar systems
(1976)
Rate constants for the mutarotation of a-D-giucose and B-D-glucose in dipolar aprotic solvent: N,N-dimethylacetamide (DMAC) in the presence of dodecylammonium propionate is greater by a factor of 2,500 for α-anomer and ...
Stereoselective electrophilic reactions using azaallyllithium reagents generated from acyclic imidate esters
(1983)
The generation and synthetic utility of azaallyllithium reagents from acyclic imidate esters was described. The acyclic imidate esters 5-15, 18-22, 31-33, 34, 36 and 37 were prepared by various methods. Azaallyllithium ...
A new method for the simultaneous determination of pyrite content and proximate analysis in coal and lignite
(1983)
Coal Analysis is ordinarily divided into three parts: (1) Proximate analysis, determination of moisture, volatile matter, fixed carbon and ash contents; (2) Ultimate analysis, determination of carbon, hydrogen, sulfur, ...
Chemical fixation of dinitrogen under mild conditions
(1978)
Chemical fixation of dinitrogen has been performed under mild conditions in homogeneous and heterogeneous systems. In heterogeneous system electron donor-acceptor complexes of iron phthalocyanine, ruthenium phthalocyanine, ...
A study of the preparation and of certain properties of the halozincate complexes
(1964)
A general method of preparation of the salts of the chlorozincate, bromozincate and iodozincate ions has been proposed and illustrated. The salts listed below have been prepared, analyzed, and characterized. Tetrachlorozincate ...
The partial oxidation of methanol to formaldehyde over molybdenum-containing catalysts
(1982)
The selective oxidation of methanol to formaldehyde over molybdenum-containing catalysts, such as silica-supported molybdenum oxide and unsupported molybdenum oxides, was studied. This dissertation describes (1) the role ...
The Diels-Alder reactions of trialkyl 3-phosphonoacrylates
(1976)
A preparative separation of the cis- and transtrimethyl 3-phosphonoacrylates was accomplished by High Speed Liquid Chromatography (HSLC), The trans-trimethyl 3-phosphonoacrylate was treated with cyclopentadiene to yield a ...