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A thermodynamic study of some aqueous monosaccharide solutions
(1979)
The heats of fusion, solubility, heats of solution at saturation and activity coefficients in binary aqueous solutions of fructose, xylose and arabinose were measured up to their saturation points at 25 °C. The activity ...
A study of the crystal lattice effects in the ¹⁴⁹Sm(n, [alpha]) ¹⁴⁶Nd reaction using thermal neutrons
(1973)
The effect of chemical form and temperature on alpha decay rates of the excited states of ¹⁵⁰Sm produced from thermal neutron capture at 0.096 eV by ¹⁴⁹Sm were studied. Targets of enriched ¹⁴⁹Sm as samarium oxide, samarium ...
The nature of the active site for the isomerization of 1-butene over magnesium oxide
(1971)
The nature of the reaction of 1-butene over MgO has been investigated. The isomerization rate at 26°C was measured in a flow system as a function of the catalyst pretreatment temperature which was varied from 300° to 900°C. ...
Several model systems for nonheme iron-sulfur proteins
(1972)
The stability and unusual electronic properties of the sulfur coordinated iron atoms in nonheme iron-sulfur proteins appear to be related to the nature of iron-sulfur bonding involving the sulfhydryl groups of the proteins ...
Approaches to the total synthesis of vernolepin
(1978)
The basic goal of this study was the development of an efficient approach to the total synthesis of vernolepin. Special attention was paid to the development of an efficient synthesis of bicycle[4.3.1]-dec-3-en-9,10-diones ...
Diorganylarsinic acids : preparation and use as extractants for gold (III) and uranium (VI)
(1977)
The new compounds dicyclohexylarsinic acid and bis(2-phenyl ethyl)- arsinic acid were prepared in 83% and 50% yields, respectively, as white crystalline materials by reacting diethylaminodichloroarsine with the appropriate ...
The stabilization energies of methyl- and fluoro- substituted allylic radicals
(1971)
The iodine catalyzed isomerization of 2,3-dimethylbutene-1 (DMB-1) to 2,3-dimethyl-butene-2 (DMB-2) has been investigated over the temperature range 408 to 564 K. The equilibrium constants for this reaction, DMB-1 [equilibrium] ...
Reactions of aqueous iodine
(1973)
The rate of disappearance of iodine or triiodide was measured by mixing either OH⁻, Hg(II), H₃AsO₃, or H₂O₂ with the iodine solutions. It was expected that these species would shift the hydrolysis equilibrium, and that the ...
Excess thermodynamic properties of binary liquid mixtures of ethylene diamine + ethylene glycol
(1972)
The refraction indices of the binary liquid mixtures of ethylene diamine + ethylene glycol were measured at 25°C. Large deviations from linearity were observed in the graphical plot of refractive index versus mole fraction. ...
A model for photodissociation dynamics applied to the potassium iodide system
(1975)
The objective of this investigation was to study the laser-induced photodissociation of potassium iodide in the vapor phase. The KI system was selected because of the high absorption cross-section and low enough bond energy ...