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Mechanisms of transition-metal catalyzed additions to olefins
(Texas A&M University, 2005-08-29)
Transition metal catalyzed reactions have an important place in synthetic chemistry, but the
mechanistic details for many of these reactions remain undetermined. Through a combination of
experimentally determined 13C kinetic ...
Supramolecules with dimolybdenum or chiral dirhodium units
(Texas A&M University, 2007-04-25)
This dissertation concerns the syntheses and characterization of supramolecules with quadruply bonded Mo2 4+ units, Mo2(DAniF)3
+ (DAniF = N,N'-di-p-anisylformamidinate) or cis-
Mo2(DAniF)2 2+, and chiral organometallic ...