Abstract
Resolution of emulsions through electrostatic coalescence has been in practice for over fifty years. Through dimensional analysis of a charged droplet under an external field, the electrical conductivity was determined to be an influencing parameter on the rate of coalescence. Using previously established procedures, the potential for enhancement of the electrostatic coalescence rate for oil/water emulsions of highly refined oils and different grades of crude oils was explored using a 2-L vertically-oriented, cylindrical coalescer. The electrical conductivity of each phase of the water-in-oil emulsion was varied to determine their effects on the rate of coalescence. Both light and intermediate grades of crude oil emulsions were modified using conductivity modifiers, formerly used as antistatic addiitvties , to change the conductivity of the oil phase. Addition of the active component of the conductivity modifier in the ppm range increased the coalescence rate from 200% to 500% as compared to the base case (no additive). The refined oil emulsion was varied using water in different conductivity ranges. As anticipated, the rate of coalescence increased with water conductivity of the water. This is at least partially due to the unstable nature of these emulsions.
Nelson, James B (1998). Conductivity factor in the electrostatic coalescence of crude oil emulsions. Master's thesis, Texas A&M University. Available electronically from
https : / /hdl .handle .net /1969 .1 /ETD -TAMU -1998 -THESIS -N45.