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Alkylation of [beta]-Diketone dicarbanions with haloacetals and halodioxolanes to form [gamma]-derivatives
| dc.contributor.advisor | Glazener, Everett R. | |
| dc.creator | Flannery, Richard Edward | |
| dc.date.accessioned | 2020-01-08T17:44:38Z | |
| dc.date.available | 2020-01-08T17:44:38Z | |
| dc.date.created | 1971 | |
| dc.date.issued | 1971 | |
| dc.identifier.uri | https://hdl.handle.net/1969.1/DISSERTATIONS-171045 | |
| dc.description.abstract | β-Diketones such as acetyl- and benzoylacetone have previously been alkylated at their methyl group instead of at their more acidic methylene group by employing, as intermediates, their dicarbanions instead of their monocarbanions. The alkylating agents in the previous cases contained carbon, hydrogen, and halogen. The present study extends the usefulness of this reaction to include haloacetals and halodioxolanes. The reactions of the halodioxolanes with disodioacetylacetone were found to be dependent on the structure of the alkylating agent. 2- (Bromo- or chloromethyl) -2- methyl-1, 3-dioxolane (XXV, X = Br or Cl, n =1 ) ... | en |
| dc.format.extent | 119 leaves | en |
| dc.format.medium | electronic | en |
| dc.format.mimetype | application/pdf | |
| dc.language.iso | eng | |
| dc.rights | This thesis was part of a retrospective digitization project authorized by the Texas A&M University Libraries. Copyright remains vested with the author(s). It is the user's responsibility to secure permission from the copyright holder(s) for re-use of the work beyond the provision of Fair Use. | en |
| dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | |
| dc.subject.classification | 1971 Dissertation F585 | |
| dc.title | Alkylation of [beta]-Diketone dicarbanions with haloacetals and halodioxolanes to form [gamma]-derivatives | en |
| dc.type | Thesis | en |
| thesis.degree.discipline | Chemistry | en |
| thesis.degree.grantor | Texas A&M University | en |
| thesis.degree.name | Doctor of Philosophy | en |
| thesis.degree.level | Doctoral | en |
| dc.contributor.committeeMember | Boone, James L. | |
| dc.contributor.committeeMember | Earle, James H. | |
| dc.contributor.committeeMember | Hawkins, Leslie V. | |
| dc.type.genre | dissertations | en |
| dc.type.material | text | en |
| dc.format.digitalOrigin | reformatted digital | en |
| dc.publisher.digital | Texas A&M University. Libraries |
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