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The hydrothermal preparation and X-ray crystal structure determination of some Cu(I) and Cu(II) ammonium halides
| dc.contributor.advisor | Johnson, G. R. | |
| dc.creator | Clayton, William Rex | |
| dc.date.accessioned | 2020-01-08T17:45:02Z | |
| dc.date.available | 2020-01-08T17:45:02Z | |
| dc.date.created | 1971 | |
| dc.identifier.uri | https://hdl.handle.net/1969.1/DISSERTATIONS-170200 | |
| dc.description.abstract | Reactions of Cu₂(OH)₃X(s) with NH₄X(5m, aq) (X = Br or Cl) have been carried out in sealed tubes in an autoclave at temperatures between 100 and 300°C, for times between 6 and 48 hours. Crystal growth of the starting material was observed, as well as the formation of single crystals of CuBr₂[dot]2NH₄Br[dot]2NH₃, Cu(NH₃)₄(CuBr₂)₂ and CuBr[dot]1/2NH₃ in the bromide system, and CuCl₂[dot]2NH₄Cl[dot]2NH₃, CuCl₂[dot]NH₄Cl[dot]2NH₃, Cu(NH₃)₄(CuCl2)₂[dot]H₂O and CuCl[dot]1/2NH₃ in the chloride system. The stoichiometry of the compounds produced was established by a combination of chemical analyses, X-ray measurements of unit cell dimensions and determinations of the densities of the solids. A brief discussion of some of the thermodynamic properties of the systems is given. ... | en |
| dc.format.extent | 173 leaves | en |
| dc.format.medium | electronic | en |
| dc.format.mimetype | application/pdf | |
| dc.language.iso | eng | |
| dc.rights | This thesis was part of a retrospective digitization project authorized by the Texas A&M University Libraries. Copyright remains vested with the author(s). It is the user's responsibility to secure permission from the copyright holder(s) for re-use of the work beyond the provision of Fair Use. | en |
| dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | |
| dc.subject.lcsh | Social sciences--Study and teaching | en |
| dc.subject.lcsh | Education--Curricula | en |
| dc.title | The hydrothermal preparation and X-ray crystal structure determination of some Cu(I) and Cu(II) ammonium halides | en |
| dc.type | Thesis | en |
| thesis.degree.discipline | Chemistry | en |
| thesis.degree.grantor | Texas A&M University | en |
| thesis.degree.name | Doctor of Philosophy | en |
| thesis.degree.level | Doctoral | en |
| dc.contributor.committeeMember | Barker, D. G. | |
| dc.contributor.committeeMember | Campbell, J. K. | |
| dc.contributor.committeeMember | David, D. W. | |
| dc.contributor.committeeMember | Lang, H. H. | |
| dc.type.genre | dissertations | en |
| dc.type.material | text | en |
| dc.format.digitalOrigin | reformatted digital | en |
| dc.publisher.digital | Texas A&M University. Libraries |
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