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Stereoselective electrophilic reactions using azaallyllithium reagents generated from acyclic imidate esters
(1983)
The generation and synthetic utility of azaallyllithium reagents from acyclic imidate esters was described. The acyclic imidate esters 5-15, 18-22, 31-33, 34, 36 and 37 were prepared by various methods. Azaallyllithium ...
A total synthesis of racemic trichodiene
(1984)
A highly stereoselective, convergent synthesis of ( )-trichodiene was developed using a Lewis acid catalyzed Nazarov cyclization to form the adjacent quaternary centers with the correct stereochemistry. The dienone ...
The synthesis and characterization of thio sugar esters of diorganylarsinous acids
(1978)
The synthesis of thiosugars containing several diorganylarsino groups is described. The compounds prepared are: dihexadecyl-, di-n-octyl-, dicyclohexyl-, dibutyl-, dipropyl-, diethyl-, methyl-npropyl- and 2-hydroxyethylm ...
Synthetic applications of photocyclizations reactions : N-allyliminium salt photocyclizations and intramolecular photoarylation of N-haloarylethyl-[beta]-enaminones
(1981)
The development and application of synthetic methods utilizing N-allyliminium salt photocyclization reactions for the construction of spiro-heterobicyclic ring systems and intramolecular photoarylation of N-haloarylethyl ...