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The development and use of a trochoidal electron spectrometer for in-beam e-y coincidence measurements
(1977)
A broad-range trochoidal spectrometer, which has been used previously for prompt and delayed in-beam studies of conversion-electron spectra, has been adapted for use in the coincidence mode. After initial development of ...
The ion-exchange and catalytic properties of titanium phosphates and mixed titanium-zirconium phosphates
(1980)
[alpha]-Titanium phosphate, Ti(HPO4)2 * H2O, has layered structure isomorphous with [alpha]-zirconium phosphate, Zr(HPO4)2 * H2O. Thus, solid solutions of the two compounds were prepared and their properties correlated ...
The catalytic behaviors of lanthanum and neodymium oxides for dehydrogenation/dehydration of ethanol
(1985)
The ethanol dehydrogenation and dehydration reactions have been employed to investigate the nature and behavior of catalytically active sites on lanthanum and neodymium sesquioxides. In support of this objective, x-ray ...
The analysis of mixed associations of aqueous nucleoside solutions
(1985)
Two similar chemical interactions were studied: (1) that between two naturally occurring nucleosides found in deoxyribonucleic acids, 2'-deoxyadenosine and thymidine; and (2) between the nucleoside 2'-deoxyadenosine and ...
Formation and reactions of lithium pyridinylcarbonyl tetracarbonylferrate
(1977)
The reaction of phenyllithium-pyridine intermediate, 1-lithio-2-phenyl-1,2-dihyropyridine, with pentacarbonyliron gave an anionic pyridinylcarbonyl iron complex. Although the isolation of the complex was unsuccessful, the ...
Characterization and catalytic activity for ammonia synthesis of ruthenium ion-exchanged zeolites
(1990)
Ruthenium metal on a zeolite support was found to be active for the catalytic synthesis of ammonia from dihydrogen and dinitrogen at temperature between 300 and 450°C and at atmospheric pressure. A triply-promoted iron ...
Methanation of carbon monoxide catalyzed by ruthenium and ruthenium alloys supported on zeolites
(1977)
The catalytic activity of supported ruthenium and a series of supported ruthenium-nickel and ruthenium-copper alloys were investigated for the reaction of carbon monoxide with hydrogen to form methane. Kinetic data were ...
Insertion and oxidative addition reactions of anionic group 6 complexes
(1987)
The anionic group 6 alkyl and aryl complexes cis-RM(CO)₄L⁻ (where M = W or Cr; R = Me, Et, or Ph; L = CO, P(OMe)₃, or PMe₃) have been shown to perform insertion of CO₂, CO, and SO₂ into the metal-alkyl (-aryl) bond. The ...
The crystal structures of two salts with large multi-atom ions: diphenyliodonium nitrate and isobutylammonium monoacidbis-[N, N'-bis(isobutyl)diamidodiselenophosphate]
(1972)
The structure of diphenyliodonium nitrate, (C₆H₅)₂INO₃, has been determined from X-ray single-crystal diffractometer data. The crystals are orthorhombic, space group Fdd2. The unit-cell constants are: a = 31.906(6), b = ...