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NMR studies and rotational isomerism in fluoroacetones
(1970)
The subject matter of this dissertation is an NMR study of α-haloacetones. In order to probe into the related structural questions of rotational isomerism, configurational equilibria, conformational analysis, etc., proton ...
Stereochemical studies of coordination complexesI. Spectropolarimetric kinetics of coordination complex ligand exchange reactions II. Nonaqueous synthesis of coordination complexes
(1970)
D-(-)Trans-1,2-cyclohexanediaminetetraacetic acid (D(-)CDTA) was prepared stereospecifically in good yield by the condensation of the resolved base, D-(-)trans-1,2-cyclohexanediamine, with sodium chloroacetate at 16°C, ...
Vibrational spectra of some small-ring compounds
(1970)
The synthesis of a series of structurally related deuterium-substituted small-ring hydrocarbons is reported. These include ethylene-(underlined "d"₂)-cyclobutane-(underlined "d"₆), methylene- (underlined "d"₂)-cycl ...
Preparation, electronic structures, and photochemistry of transition metal carbonyl complexes
(1975)
The research consisted of three related investigations: l) the preparation and characterization of new carbonyl complexes, 2) the assignment of the electronic spectra and structure of the new complexes along with some ...
The dynamic carbon-13 nuclear magnetic resonance spectroscopy of some organometallic compounds
(1975)
The fluxional behavior of 1, 3, 5, 7-tetramethylcyclooctatetraene-tricarbonylchromium, (TMCOT)Cr(CO)₃, previously shown by ¹H NMR to be based on a single, reversible type of 1, 2-shift has been reexamined with ¹³C ...
Kinetic and thermodynamic study of the interaction of vitamine B₁₂a with ligands in aqueous and micellar environments
(1976)
Rate constants for the formation, k₁(superscript app) and decomposition, k₋ ₁(superscript app), of glycine, imidazole, sodium azide, cysteine, N-butanoyl-D,L-cysteine, N-octanoyl-D,L-cysteine, and N-decanoyl-D,L-cysteine ...
The electrochemical oxidation of 10[beta]-methyl-1[beta]-trans-decalol
(1978)
The electrochemical oxidation of 10β-methyl-lβ-trans-decalol (11) has been investigated using the aqueous acetonitrile - tetraethylammonium tetrafluoroborate electrolytic system with controlled and noncontrolled potential ...
Ammonia oxidation and nitric oxide reduction over Cu(II)Nay zeolites
(1976)
The catalytic activity of Cu(II)NaY zeolites in the oxidation of ammonia by molecular oxygen and by nitric oxide has been investigated for a series of copper-exchanged Y zeolites. Kinetic data were determined for the ...
NMR studies and conformational analysis: the use of Lanthanide Shift Reagents
(1975)
The use of Lanthanide Shift Reagents for the NMR-based conformational analysis of three different substituted cyclohexanones and their tertiary alcohol derivatives is described. The three cyclohexanones, 5,5-dimethyl-3-( ...