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    Porous polymer network materials

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    9409116.pdf (1.118Mb)
    Date
    2016-08-09
    Author
    Zhou, Hong-cai
    Sculley, Julian
    Lu, Weigang
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    Abstract
    Functionalized Porous Polymer Networks (PPNs) exhibiting favourable characteristics such as high surface area′ and gas uptake properties are disclosed, including methods of making such networks. A method of preparing a porous polymer network, comprising: (a) a step of homo-coupling a monomer in the presence of 2,2′-bipyridyl, 1,5-cycloocta-1,5-diene, a mixed solvent of DMF/THF and a compound or mixture selected from the group consisting of bis(1,5-cydoocta-1,5-diene)nickel(0), Ni(PPH3) 4, and Zn/NiCI2/NaBr/PPH3 at a temperature in the range of 20 to 40° C. These stable PPNs may be useful in the context of carbon capture, gas storage and separation, and as supports for catalysts.
    URI
    https://hdl.handle.net/1969.1/177163
    Subject
    B01D 53/04
    B01D 53/02
    B01J 20/265
    B01J 20/267
    B01J 20/28066
    C08J 9/00
    F17C 11/007
    B01D 2253/202
    B01D 2256/10
    B01D 2257/504
    B01D 2257/7025
    B01D 2259/4525
    C08J 2365/00
    C08J 2383/00
    C08J 2385/00
    Y02C 10/08
    Y02C 20/20
    Y02P 20/152
    Y02P 20/156
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    • Texas A&M University Patents
    Citation
    Zhou, Hong-cai; Sculley, Julian; Lu, Weigang (2016). Porous polymer network materials. United States. Patent and Trademark Office; Texas A&M University. Libraries. Available electronically from https : / /hdl .handle .net /1969 .1 /177163.

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