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The solubilization of transition-metal complexes into aqueous media for use in biphasic catalytic systems
(1994)
The water-soluble phosphine complex of ruthenium(II), RuCl2(PTA)4, has been prepared by the reduction of RuCl3 in ethanol in the presence of the air-stable phosphine 1,3,5-triaza-7-phosphaadamantane. RuCl2(PTA)4 is an ...