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Synthesis and characterization of sulfur-capped trinuclear molybdenum and tungsten clusters
(1992)
The synthesis of molybdenum and tungsten trinuclear clusters is presented. The clusters of interest contain a M3(μ3-S)(μ2-S2)3[^4+] core with nine terminal ligands, i. e. three bound to each metal center. The ligands ...
Electronic structure and reaction mechanism of transition metal complexes : bond-stretch isomerism, methane activation on transient cyclopentadienylcarbonylrhodium, and ligand substitutions on metal nitrosyl carbonyl complexes
(1992)
Ab initio molecular orbital techniques are utilized to investigate the electronic structure and reaction mechanism of transition metal complexes. Our calculations at the levels of the restricted Hartree-Fock (RHF) and ...