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Synthesis and characterization of sulfur-capped trinuclear molybdenum and tungsten clusters
(1992)
The synthesis of molybdenum and tungsten trinuclear clusters is presented. The clusters of interest contain a M3(μ3-S)(μ2-S2)3[^4+] core with nine terminal ligands, i. e. three bound to each metal center. The ligands ...
Synthesis, characterization, and structure of molybdenum and tungsten trinuclear compounds with more than six cluster electrons
(1992)
Synthetic methods for a series of new M3X13 type triangular trinuclear clusters with eight cluster electrons and a core of M3OX3 (M = Mo, W; X = Cl, Br) are described in this dissertation. The methods employed in the ...