Browsing by Subject "Organometallic"
Now showing items 1-2 of 2
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(2014-08-20)The discovery of a diiron organometallic active site, found in the [FeFe]-Hydrogenase (H2ase) enzyme, has led to a revisiting of the classic organometallic chemistry involving the Fe-Fe bond and bridging ligands. This ...
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(2016-12-08)The discovery of cyano-iron carbonyls in the hydrogenases has inspired synthetic efforts to reproduce the active sites of these efficient H2-producing or H2-oxidation enzymes. Recent demonstration of the possibility of ...