Browsing by Subject "Isotope Effects"
Now showing items 1-3 of 3
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(2009-05-15)Unfortunately, chemists can never experimentally unravel a full reaction pathway. Even our ability to define key aspects of mechanisms, such as short-lived intermediates and the even more ephemeral transition states, is ...
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(2010-01-16)The research presented provides a method to use the comparison of intermolecular isotope effects vs. the intramolecular isotope effects for the study of reactions in which study of the rate limiting step is ambiguous due ...
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(2013-12-09)In this dissertation, experimental probes and theoretical calculations have been applied to delineate mechanisms of various [2+2] cycloadditions. Besides common experimental observations and transition state theories, this ...