Nitrogen-containing aromatic heterocyclic ligand-metal complexes and their use for the activation of hydrogen peroxide and dioxygen in the reaction of organic compounds
Abstract
Nitrogen-containing aromatic heterocyclic ligand-metal complexes and their use for the activation of hydrogen peroxide and dioxgen are disclosed. Processes whereby activated hydrogen peroxide or dioxygen are used to transform various organic substrates are also disclosed. In particular, processes for the conversion of methylenic carbons to carbonyls, for the dioxygenation of aryl olefins, acetylenes and aryl-α-diols, for the oxidation of alcohols and aldehydes and for the removal of mercaptans from gaseous streams and for the removal of hydrogen sulfide and/or mercaptans from liquid streams are disclosed.
Subject
568/342568/311
568/320
568/360
568/385
568/399
568/400
568/401
568/431
568/815
568/818
568/822
568/910
B01D 53/1493
C07C 37/60
C07C 45/28
C07C 45/294
C07C 45/33
C07C 45/34
C07C 45/36
C07C 45/38
C07C 45/39
C07C 46/06
C07C 51/16
C07C 51/285
C07C 245/08
C07D 303/04
C07C 50/02
C07C 37/60
C07C 39/04
C07C 2601/14
Collections
Citation
Sawyer, Donald T.; Sheu, Ceshing; Sobkowiak, Andrzej; Tung, Hui-Chan (1992). Nitrogen-containing aromatic heterocyclic ligand-metal complexes and their use for the activation of hydrogen peroxide and dioxygen in the reaction of organic compounds. United States. Patent and Trademark Office; Texas A&M University. Libraries. Available electronically from https : / /hdl .handle .net /1969 .1 /177286.