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dc.contributor.advisorChirayath, Sunil S.
dc.contributor.advisorBurns, Jonathan D.
dc.creatorWilcox, Andrew John
dc.date.accessioned2019-01-17T21:26:55Z
dc.date.available2020-05-01T06:25:44Z
dc.date.created2018-05
dc.date.issued2018-05-09
dc.date.submittedMay 2018
dc.identifier.urihttps://hdl.handle.net/1969.1/173608
dc.description.abstractThe development of a group actinide separation of U, Pu, Np, and Am could significantly simplify the closure of the nuclear fuel cycle, while reducing the amount of nuclear waste produced. To perform this group extraction the difficult separation of Am^3+ from Cm^3+ and the trivalent lanthanides must be addressed. Higher oxidation states of Am have been observed but require a high oxidizing potential to achieve. NaBiO3 has been shown to be capable of oxidation of Am(III)/Am(VI) in highly concentrated nitric acid and is known to be a cost effective and easily produced oxidizing agent. The slow dissolution kinetics of sodium bismuthate that have been observed, as well as its low solubility in nitric acid, represent some concerns in adoption of a process in which it is implemented. For this reason a thorough investigation of these properties as a function of nitric acid concentrations was undertaken. In addition, the effect of having other metal ions present in solution, like Cs^+, Sr^2+, Nd^3+, Zr^4+, Ce^3+/^4+, or UO22+ on the dissolution behavior of sodium bismuthate was determined. Except in the case of Sr^2+ these metal ions were seen to reduce the solubility limit of sodium bismuthate to varying degrees, while each ion was also found to either have a neutral or positive effect on the dissolution rate.en
dc.format.mimetypeapplication/pdf
dc.language.isoen
dc.subjectSodium Bismuthateen
dc.titleThe Kinetic and Thermodynamic Properties of the Dissolution of Sodium Bismuthateen
dc.typeThesisen
thesis.degree.departmentNuclear Engineeringen
thesis.degree.disciplineNuclear Engineeringen
thesis.degree.grantorTexas A & M Universityen
thesis.degree.nameMaster of Scienceen
thesis.degree.levelMastersen
dc.contributor.committeeMemberFolden, Charles M.
dc.type.materialtexten
dc.date.updated2019-01-17T21:26:55Z
local.embargo.terms2020-05-01
local.etdauthor.orcid0000-0002-6467-2119


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