Browsing by Subject "iridium"
Now showing items 1-6 of 6
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(2015-01-22)The importance of organoboron compounds in chemical synthesis is apparent from the Nobel Prizes awarded to Herbert C. Brown (1979) and Akira Suzuki (2010) for their contribution to the development of new synthetic methodologies ...
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(2019-10-01)The use of Z-ligands to modulate the electronic property of transition metal centers is a powerful strategy in catalyst design. Our group has shown that antimony-based ambiphilic ligand, accept electron density from adjacent ...
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(2021-08-18)Metal-catalyzed cross-coupling reactions of aryl halides or pseudohalides with nucleophiles have been ubiquitous and powerful tools to construct new C–C bonds in synthetic organic chemistry. Among the nucleophiles, arylboronic ...
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(2016-08-04)Over the last century, transition metal-catalyzed C-H functionalization has emerged as one of the most important topics in synthetic chemistry. One type of C-H functionalization, known as C-H borylation, generates organoboron ...
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(2009-05-15)Asymmetric hydrogenation as a general route to polypropionates has been explored for allylic alcohols, acids, and derivatives, which has led to the generation of 2,4-dimethylated hexane derivatives. Quantitative yields in ...
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(2013-11-05)N-Heterocyclic carbene and phosphorus ligands have been synthesized and used for many catalytic reactions including chiral analogs of Crabtree’s catalyst for asymmetric hydrogenation. These catalysts have been ...